Electronic modifications in (Ba,La)(Fe,Zn,Y)O<sub>3−<i>δ</i></sub> unveiled by oxygen K-edge X-ray Raman scattering

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چکیده

Triple-conducting perovskites: Fe 3d–O 2p hybridization affects proton uptake – a larger O → electron transfer decreases 2− basicity. O-XRS elucidates effects of oxidation state and oversized dopants.

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ژورنال

عنوان ژورنال: Journal of materials chemistry. A, Materials for energy and sustainability

سال: 2022

ISSN: ['2050-7488', '2050-7496']

DOI: https://doi.org/10.1039/d1ta10211g